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Principles of Inorganic Chemistry II, Fall 2008
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CC BY-NC-SA
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" This course provides a systematic presentation of the chemical applications of group theory with emphasis on the formal development of the subject and its applications to the physical methods of inorganic chemical compounds. Against the backdrop of electronic structure, the electronic, vibrational, and magnetic properties of transition metal complexes are presented and their investigation by the appropriate spectroscopy described."

Subject:
Chemistry
Physical Science
Material Type:
Full Course
Textbook
Author:
Nocera, Daniel
Date Added:
01/01/2008
Small-Molecule Spectroscopy and Dynamics
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The goal of this course is to illustrate the spectroscopy of small molecules in the gas phase: quantum mechanical effective Hamiltonian models for rotational, vibrational, and electronic structure; transition selection rules and relative intensities; diagnostic patterns and experimental methods for the assignment of non-textbook spectra; breakdown of the Born-Oppenheimer approximation (spectroscopic perturbations); the stationary phase approximation; nondegenerate and quasidegenerate perturbation theory (van Vleck transformation); qualitative molecular orbital theory (Walsh diagrams); the notation of atomic and molecular spectroscopy.

Author:
Prof. Robert Field
A Spectral Mystery
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Students use the spectrographs from the "Building a Fancy Spectrograph" activity to gather data about light sources. Using their data, they make comparisons between different light sources and make conjectures about the composition of a mystery light source.

Author:
Laboratory for Atmospheric and Space Physics, University of Colorado at Boulder
Laboratory for Atmospheric and Space Physics (LASP),
Spectroscopy
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Spectroscopy is the study of the interaction between matter and electromagnetic radiation. Molecules respond to different types of radiation in different ways, depending on the frequency - or wavelength - of the radiation. This one-semester course is designed to provide you with a more thorough description of the theory behind each spectroscopic technique as well as its applications. Upon successful completion of this course, the student will be able to: Discuss similarities and differences between spectrometry and spectroscopy; Identify the basic components of spectroscopic instrumentation; Demonstrate a working knowledge of mass spectroscopy (MS), ultraviolet-visible (UV-Vis) spectroscopy, infrared (IR) spectroscopy, and nuclear magnetic resonance (NMR) spectroscopy; Describe how a mass spectrometer produces its spectral patterns; Explain the information obtained from a UV-Vis spectrophotometer and how it can be used for analysis; Illustrate the mechanisms that give rise to the infrared absorption bands and identify to which functional groups each correspond; Demonstrate an understanding of the processes responsible for NMR chemical shifts and splitting patterns; Elucidate the structures of organic molecules from spectral data. (Chemistry 205)

Spectroscopy: Lecture 1
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Chapter 13: Spectroscopy. Lecture 1
Carey, F. A. ; Giuliano, R. M. in Organic Chemistry, 8th Ed, 2011
By Professor Bilal R. Kaafarani

Author:
Prof. Bilal R. Kaafarani
Using Spectral Data to Explore Saturn and Titan
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Students use authentic spectral data from the Cassini mission of Saturn and Saturn's moon, Titan, gathered by instrumentation developed by engineers. Taking these unknown data, and comparing it with known data, students determine the chemical composition of Saturn's rings and Titan's atmosphere.

Author:
Laboratory for Atmospheric and Space Physics, University of Colorado at Boulder
Laboratory for Atmospheric and Space Physics (LASP),
Using a Fancy Spectrograph
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Students use the spectrograph from the "Building a Fancy Spectrograph" activity to gather data about different light sources. Using the data, they make comparisons between the light sources and make conjectures about the composition of these sources.

Author:
LASP (primary author)
Laboratory for Atmospheric and Space Physics (LASP),
Emily Gill (later addition)